配体促进的过渡金属催化芳烃远程meta-C—H键官能化反应研究进展

doi:10.6023/cjoc201909015

有机化学 ›› 2020, Vol. 40 ›› Issue (3): 625-644.DOI: 10.6023/cjoc201909015 上一篇下一篇

综述与进展

配体促进的过渡金属催化芳烃远程meta-C—H键官能化反应研究进展

田万发^b, 李娜^a, 彭子赫^c, 冯丽华^a, 麦曦^a, 贺永勤^a

a 南昌大学药学院南昌 330000;
b 江西科技师范大学有机功能分子重点实验室南昌 330000;
c 南昌大学抚州医学院江西抚州 344000

收稿日期:2019-09-09 修回日期:2019-11-27 发布日期:2019-12-19
通讯作者: 贺永勤 E-mail:heyq12@lzu.edu.cn
基金资助:
国家自然科学基金（No.81860610）和南昌大学医学部青年教师培育基金（No.4209-16100009-PY201810）资助项目.

Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C—H Functionalization of Arenes

Tian Wanfa^b, Li Na^a, Peng Zihe^c, Feng Lihua^a, Mai Xi^a, He Yongqin^a

a School of Pharmaceutical Science, Nanchang University, Nanchang 330000;
b Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330000;
c Fuzhou Medical College, Nanchang University, Fuzhou, Jiangxi 344000

Received:2019-09-09 Revised:2019-11-27 Published:2019-12-19
Supported by:
Project supported by the National Natural Science Foundation of China (No. 81860610) and the Young Teachers Training Foundation of Nanchang University (No. 4209-16100009-PY201810).

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摘要/Abstract

过渡金属催化C—H活化反应中，配体能够对催化中心的空间及电子效应进行调控，从而实现芳烃C—H键的选择性官能化.近年来，配体促进芳烃远程C—H键官能化反应研究有了新的进展.对近几年来配体促进的过渡金属催化芳烃远程meta-C—H键选择性官能化反应进行了系统总结，并对该研究领域的局限性和未来的发展前景进行总结和展望.

关键词: 过渡金属催化, 远程meta-C—H键, 官能化反应, 配体促进

Ligands can regulate both the steric and electronic effects of the catalytic center in transition-metal-catalyzed C-H activation reactions, leading to the site-selective C-H functionalization of arenes. In recent years, ligand-promoted remote C-H functionalization of arenes has developed rapidly. The recent progress on ligand-promoted transition-metal-catalyzed remote meta-selective C-H bond functionalization of arenes is summarized, and the limitations of the research field and prospects for future development are presented.

Key words: transition metal catalysis, remote meta-C—H bond, functionalization, ligand promotion

引用此文

田万发, 李娜, 彭子赫, 冯丽华, 麦曦, 贺永勤. 配体促进的过渡金属催化芳烃远程meta-C—H键官能化反应研究进展[J]. 有机化学, 2020, 40(3): 625-644.

Tian Wanfa, Li Na, Peng Zihe, Feng Lihua, Mai Xi, He Yongqin. Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C—H Functionalization of Arenes[J]. Chinese Journal of Organic Chemistry, 2020, 40(3): 625-644.

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配体促进的过渡金属催化芳烃远程meta-C—H键官能化反应研究进展

Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C—H Functionalization of Arenes

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