新型高效咪唑希夫碱缓蚀剂对<strong>Q235</strong>钢在<strong>1 mol/L HCl</strong>溶液中的缓蚀作用

doi:10.11902/1005.4537.2023.063

中国腐蚀与防护学报

2024, Vol. 44

Issue (1): 59-70 CSTR: 32134.14.1005.4537.2023.063 DOI: 10.11902/1005.4537.2023.063

研究报告

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新型高效咪唑希夫碱缓蚀剂对Q235钢在1 mol/L HCl溶液中的缓蚀作用

王鹏杰¹^,², 宋昱灏¹^,², 樊林¹^,², 邓宽海², 李忠慧³, 梅宗斌⁴, 郭雷⁵, 林元华¹^,²^,³(

)

^1.西南石油大学油气藏地质及开发工程国家重点实验室成都 610500
^2.西南石油大学新能源与材料学院成都 610500
^3.长江大学石油工程学院武汉 434023
^4.四川华宇钻采装备有限公司泸州 646000
^5.铜仁学院材料与化学工程学院铜仁 554300

Inhibition of Q235 Steel in 1 mol/L HCl Solution by a New Efficient Imidazolium Schiff Base Corrosion Inhibitor

WANG Pengjie¹^,², SONG Yuhao¹^,², FAN Lin¹^,², DENG Kuanhai², LI Zhonghui³, MEI Zongbin⁴, GUO Lei⁵, LIN Yuanhua¹^,²^,³(

)

^1.State Key Laboratory of Oil and Gas Reservoir Geology and Development Engineering, Southwest Petroleum University, Chengdu 610500, China
^2.School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China
^3.School of Petroleum Engineering, Changjiang University, Wuhan 434023, China
^4.Sichuan Huayu Drilling and Production Equipment Co., Ltd., Luzhou 646000, China
^5.Materials and Chemical Engineering, Tongren University, Tongren 554300, China

引用本文:

王鹏杰, 宋昱灏, 樊林, 邓宽海, 李忠慧, 梅宗斌, 郭雷, 林元华. 新型高效咪唑希夫碱缓蚀剂对Q235钢在1 mol/L HCl溶液中的缓蚀作用[J]. 中国腐蚀与防护学报, 2024, 44(1): 59-70.
Pengjie WANG, Yuhao SONG, Lin FAN, Kuanhai DENG, Zhonghui LI, Zongbin MEI, Lei GUO, Yuanhua LIN. Inhibition of Q235 Steel in 1 mol/L HCl Solution by a New Efficient Imidazolium Schiff Base Corrosion Inhibitor[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 59-70.

全文: PDF(9316 KB) HTML

摘要:

以油酸、二乙烯三胺、碘代正丁烷和肉桂醛等为原料，在不同温度下进行酰胺化、脱水环化、季铵化等过程设计合成一种适用于酸洗工况的咪唑希夫碱(MIX)缓蚀剂，通过失重实验、电化学实验、理论模拟和表面分析等方法系统的探究了MIX在1.00 mol/L HCl溶液中对Q235钢的缓蚀性能及其缓蚀机理。结果表明：在浓度为2.00 mmol/L时，采用失重实验，电化学阻抗(EIS)，动电位极化(Tafel)测得的缓蚀效率分别为98.64%，96.93%和99.15%，表明MIX在HCl环境中能够发挥优异的缓蚀性能。电化学实验和等温吸附模型表明，MIX是一种阴极型缓蚀剂，能够自发吸附在Q235钢表面，且遵循Langmuir吸附等温模型。MIX能够在Q235钢表面形成稳定的保护膜，进一步阻碍了腐蚀体系内电荷转移速率。XPS，EDS和FT-IR分析证实了MIX分子能够吸附在Q235钢表面，密度泛函理论(DFT)说明MIX的活性位点为苯基，咪唑环上的N原子，分子动力学(MD)进一步证实了MIX能够吸附在Q235钢表面。MIX在HCl环境中能够发挥优异的缓蚀性能，主要在于Q235钢表面形成了稳定的保护膜，降低了腐蚀体系内电荷转移速率。

关键词 ：咪唑希夫碱, 电化学, 失重实验, 缓蚀性能, 理论计算

Abstract：

An imidazole Schiff base (MIX) corrosion inhibitor was synthesized via processes of amidation, dehydration cyclization, and quaternization at different temperatures with oleic acid, diethylenetriamine, n-butane iodide and cinnamaldehyde as raw material. The corrosion inhibition performance and mechanism of MIX on Q235 steel in 1.00 mol/L HCl were systematically investigated by means of mass loss measurement, electrochemical testing, and surface analysis methods, as well as theoretical simulations. The results showed that the corrosion inhibition efficiency determined by mass loss method, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization (Tafel) were 98.64%, 96.93%, and 99.15%, respectively for adding a dose of MIX 2 mmol/L in the 2.00 mmol/L HCl solution, indicating that MIX can exhibit excellent corrosion inhibition performance in HCl environments. Electrochemical testing and isothermal adsorption models indicate that MIX is a cathodic corrosion inhibitor that can spontaneously adsorb on the surface of Q235 steel, following the Langmuir adsorption isotherm model. MIX can form a stable protective film on the surface of Q235 steel, further hindering the charge transfer rate within the corrosion system. XPS, EDS and FT-IR analysis confirmed that MIX molecules may be adsorbed on the surface of Q235 steel. Density functional theory (DFT) showed that the active site of MIX was phenyl, and the N atom on the imidazole ring. Molecular dynamics (MD) further confirmed that MIX may be adsorbed on the surface of Q235 steel. MIX can exhibit excellent corrosion inhibition performance in HCl environments, mainly due to the formation of a stable protective film on the surface of Q235 steel, which reduces the charge transfer rate within the corrosion system.

Key words： imidazole Schiff base electrochemistry mass loss experiment corrosion inhibition performance theoretical calculation

收稿日期: 2023-03-10 32134.14.1005.4537.2023.063

ZTFLH:

TG174

基金资助:国家自然科学基金(52074232);四川省自然科学基金(2022NSFSC0028);中国博士后科学基金(2022M710117);四川省青年科学基金(2022NSFSC0994)

通讯作者: 林元华，E-mail：yhlin28@163.com，研究方向为油气钻井工艺和油井管材料

Corresponding author: LIN Yuanhua, E-mail: yhlin28@163.com

作者简介: 王鹏杰，男，1993年生，硕士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2023.063 或 https://www.jcscp.org/CN/Y2024/V44/I1/59

图1 MIX缓蚀剂分子的合成路线

图2 MIX的红外谱图

图3 MIX在重水中NMR:1H-NMR和13C-NMR谱

图4 Q235钢在不同MIX浓度溶液中的开路电位

图5 Q235钢在不同浓度MIX溶液中Nyquist图及其等效电路

C mmol/L	R_s Ω·cm²	Y_{0, f}× 10^-5 Ω^-1·cm^-2·sⁿ	n_f	C_f μF·cm²	R_f Ω·cm²	Y_{0, rct}× 10^-5 Ω^-1·cm^-2·sⁿ	n_rct	C_dl μF·cm²	R_ct Ω·cm²	$χ 2$	η_p
0.00	8.59	2.45	0.99	10.37	1.48	12.46	0.81	33.32	17.14	0.0015	/
0.20	1.10	4.915	0.80	9.47	73.3	11.21	0.80	21.52	267.8	0.0047	92.04%
0.50	1.41	15.26	0.79	7.87	411.1	3.66	0.74	18.72	76.84	0.0051	94.44%
1.00	2.71	8.78	0.76	5.61	83.85	17.91	0.70	11.91	696.3	0.0038	96.52%
2.00	2.46	19.45	0.72	3.67	790.3	8.44	0.71	8.32	95.37	0.0056	96.93%

表1 Q235钢在MIX不同缓蚀溶液中EIS参数

图6 Q235钢在不同MIX缓蚀溶液中的动电位极化图

Concentration / mmol·L^-1	$E c o r r$ / $V$	$I c o r r$ / mA·cm^-2	-b_c mV·dec^-1	b_a mV·dec^-1	η
0.00	-0.478	3.5410	143.76	150.26	/
0.20	-0.493	0.0827	147.95	158.05	97.66%
0.50	-0.484	0.0525	179.17	157.77	98.51%
1.00	-0.489	0.0332	201.65	145.53	99.06%
2.00	-0.493	0.0301	255.68	161.29	99.15%

表2 极化曲线参数及缓蚀效率

表3 Q235钢在不同MIX缓蚀溶液中的失重参数

图7 Langmuir、El-Awady、Flory-Huggins、Freundlich和Temkin等温吸附曲线

图8 Q235钢在不同浓度MIX缓蚀溶液中失重后的表面形貌

图9 失重后的Q235钢表面和EDS能谱

图10 失重后Q235钢表面和MIX的红外图

图11 失重后的Q235钢表面的XPS能谱

图12 MIX分子的分子结构、HOMO、 LUMO和ESP

图13 MIX在Fe(110)上的最佳吸附形态

1	Liu Q Y, Song Z J, Han H, et al. A novel green reinforcement corrosion inhibitor extracted from waste Platanus acerifolia leaves [J]. Constr. Build. Mater., 2020, 260: 119695 doi: 10.1016/j.conbuildmat.2020.119695
2	Liu D M, Yang K, Shi X, et al. Synergistic inhibition effect between 2-mercaptobenzothiazole and chloride ion in sulfuric acid solution [J]. Surf. Technol., 2021, 50(7): 351
2	刘冬梅, 杨康, 石鑫等. 硫酸溶液中2-巯基苯并噻唑与氯离子的协同缓蚀作用 [J]. 表面技术, 2021, 50(7): 351
3	Ni X L, Li H, Li Y F, et al. Corrosion protection of imidazoline corrosion inhibitors with different carbon chain lengths in CO₂ driving oil environment [J]. Surf. Technol., 2023, 52(8): 278
3	倪小龙, 李欢, 李云飞等. 不同碳链长度咪唑啉缓蚀剂在CO₂驱采油环境中的腐蚀防护作用 [J]. 表面技术, 2023, 52(8): 278
4	Ren X D, Wang H, Wei Q, et al. Electrochemical behaviour of N80 steel in CO₂ environment at high temperature and pressure conditions [J]. Corros. Sci., 2021, 189: 109619 doi: 10.1016/j.corsci.2021.109619
5	Liu M M, Yang X B, Chen X Q, et al. Research progress on corrosion behavior of metallic materials in acetic acid environment [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 13
5	刘明明, 杨小兵, 陈晓琪等. 醋酸环境下金属材料腐蚀行为的研究进展 [J]. 中国腐蚀与防护学报, 2023, 43: 13 doi: 10.11902/1005.4537.2022.186
6	Pan C G, Chen N, He J Z, et al. Effects of corrosion inhibitor and functional components on the electrochemical and mechanical properties of concrete subject to chloride environment [J]. Construct. Build. Mater., 2020, 260: 119724 doi: 10.1016/j.conbuildmat.2020.119724
7	Katiyar P K, Behera P K, Misra S, et al. Comparative corrosion behavior of five different microstructures of rebar steels in simulated concrete pore solution with and without chloride addition [J]. J. Mater. Eng. Perform., 2019, 28: 6275 doi: 10.1007/s11665-019-04339-x
8	Rangaswamy V M, Keshavayya J. Anticorrosive ability of cycloheximide on mild steel corrosion in 0.5M H₂SO₄ Solution [J]. Chem. Data Collect., 2022, 37: 100795 doi: 10.1016/j.cdc.2021.100795
9	Firdhouse M J, Nalini D. Corrosion inhibition of mild steel in acidic media by 5′-Phenyl-2′,4′-dihydrospiro [indole-3,3′-pyrazol]-2(1H)-one [J]. J. Chem., 2013, 2013: 835365
10	Saady A, Rais Z, Benhiba F, et al. Chemical, electrochemical, quantum, and surface analysis evaluation on the inhibition performance of novel imidazo [4,5-b] pyridine derivatives against mild steel corrosion [J]. Corros. Sci., 2021, 189: 109621 doi: 10.1016/j.corsci.2021.109621
11	Li R H, Wang Z X, Xu Q W, et al. Synthesis, characterization and physicochemical properties of new chiral quinuclidinol quaternary ammonium salts [J]. J. Mol. Struct., 2020, 1209: 127918 doi: 10.1016/j.molstruc.2020.127918
12	Qiang Y J, Zhang S T, Yan S, et al. Three indazole derivatives as corrosion inhibitors of copper in a neutral chloride solution [J]. Corros. Sci., 2017, 126: 295 doi: 10.1016/j.corsci.2017.07.012
13	Yang X Y, Yang Y T, Lu X P, et al. Research progress of corrosion inhibitor for Mg-alloy [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 435
13	杨欣宇, 杨云天, 卢小鹏等. 镁合金缓蚀剂研究进展 [J]. 中国腐蚀与防护学报, 2022, 42: 435 doi: 10.11902/1005.4537.2021.295
14	Zhang M, Li Q, Zhang K, et al. Corrosion inhibition properties of propylenediamine-type double mannich base acidizing corrosion inhibitor [J]. Corros. Prot., 2022, 43(6): 26
14	张萌, 李清, 张鲲等. 丙二胺型双曼尼希碱酸化缓蚀剂的缓蚀性能 [J]. 腐蚀与防护, 2022, 43(6): 26
15	Guo N N, Wang X R, Gu Y Z, et al. Research on synthesis and application of quaternary ammonium salt amphoteric Gemini surfactants [J]. Petrochem. Technol., 2021, 50: 608
15	郭乃妮, 王小荣, 古元梓等. 季铵盐型两性双子表面活性剂的合成及应用研究进展 [J]. 石油化工, 2021, 50: 608 doi: 10.3969/j.issn.1000-8144.2021.06.017
16	Li J Y, Zhao J Q, Shao H Y, et al. Synthesis of thiourido-imidazoline corrosion inhibitor and its corrosion inhibition performance [J]. Oilfield Chem., 2021, 38: 152
16	李继勇, 赵俊桥, 邵红云等. 硫脲基咪唑啉缓蚀剂的合成及其缓蚀性能 [J]. 油田化学, 2021, 38: 152
17	Cheng Y S, Xu H W, Huang C S, et al. Study on corrosion inhibition performance of water-soluble imidazoline amide on A3 steel [J]. Appl. Chem. Ind., 2023, 52: 779
17	程玉山, 徐会武, 黄长山等. 水溶性咪唑啉酰胺对A3钢的缓蚀性能研究 [J]. 应用化工, 2023, 52: 779
18	Yang Q Z, Zhang T L, Liu C S, et al. Preparation and inhibition mechanism of gemini imidazoline quaternary ammonium salt inhibitor [J]. Chem. Ind. Eng. Progress, 2023: 1-13, doi: 10.16085/j.issn.1000-6613.2022-2169
18	阳清正, 张太亮, 刘从胜等. 双子型咪唑啉季铵盐缓蚀剂的制备及缓蚀机理 [J]. 化工进展, 2023: 1-13, doi: 10.16085/j.issn.1000-6613.2022-2169
19	Lu Y, Zhang G X, Liu B S, et al. The corrosion inhibition effect of proparynol-modified midazolin on X65 steel in CO₂/H₂S co-existence system [J]. Surf. Technol., 2021, 50(7): 345
19	陆原, 张国欣, 刘保山等. 丙炔醇改性硫脲基咪唑啉在CO₂/H₂S共存体系中对X65钢的腐蚀抑制作用 [J]. 表面技术, 2021, 50(7): 345
20	Li J L, Shen Y B, Li J Y, et al. Study on the inhibitor of schiff base pyridine quaternary ammonium salt for anti-high temperature and high concentration hydrochloric acid [J]. Surf. Technol., 2021, 50(9): 303
20	李俊莉, 沈燕宾, 李霁阳等. 抗高温高浓盐酸席夫碱基吡啶季铵盐缓蚀剂的研究 [J]. 表面技术, 2021, 50(9): 303
21	Limco R A, Bacosa H P, Lubguban A A, et al. Morinda citrifolia (Noni) leaf extract as corrosion inhibitor for steel-reinforced concrete in saline environment [J]. Int. J. Environ. Sci. Technol., 2020, 17: 4531 doi: 10.1007/s13762-020-02795-w
22	Cao F T, Wei J, Dong J H, et al. Corrosion inhibition behavior of 1-hydroxyethylidene-1,1-diphosphonic acid on 20SiMn steel in simulated concrete pore solution containing Cl^- [J]. Acta Metall. Sin., 2020, 56: 898
22	曹凤婷, 魏洁, 董俊华等. 羟基亚乙基二膦酸对20SiMn钢在含Cl^-混凝土模拟孔隙液中的缓蚀行为 [J]. 金属学报, 2020, 56: 898 doi: 10.11900/0412.1961.2019.00382
23	Cao S Y, Liu D, Ding H, et al. Corrosion inhibition effects of a novel ionic liquid with and without potassium iodide for carbon steel in 0.5 M HCl solution: An experimental study and theoretical calculation [J]. J. Mol. Liquids, 2019, 275: 729 doi: 10.1016/j.molliq.2018.11.115
24	Wu H, Deng S D, Li X H. Synergistic inhibition effect of cuscuta chinensis lam extract and potassium iodide on cold rolled steel in hydrochloric acid [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 77
24	吴浩, 邓书端, 李向红. 菟丝子提取物与碘化钾对冷轧钢在盐酸中的缓蚀协同效应 [J]. 中国腐蚀与防护学报, 2023, 43: 77
25	Verma C, Quraishi M A, Ebenso E E, et al. 3-Amino alkylated indoles as corrosion inhibitors for mild steel in 1M HCl: Experimental and theoretical studies [J]. J. Mol. Liquids, 2016, 219: 647 doi: 10.1016/j.molliq.2016.04.024
26	De A, Santra S, Kovalev I S, et al. Synthesis of 2-imidazolines by co-grinding of N-tosylaziridines and nitriles [J]. Mendeleev Commun., 2020, 30: 188 doi: 10.1016/j.mencom.2020.03.019
27	Hashem M A, Elnagar M M, Kenawy I M, et al. Synthesis and application of hydrazono-imidazoline modified cellulose for selective separation of precious metals from geological samples [J]. Carbohydr. Polym., 2020, 237: 116177 doi: 10.1016/j.carbpol.2020.116177
28	Hameed R S A, Al-Bagawi A H, Shehata H A, et al. Corrosion inhibition and adsorption properties of some heterocyclic derivatives on C-steel surface in HCl [J]. J. Bio. Tribo-Corros., 2020, 6: 51
29	Kousar K, Ljungdahl T, Wetzel A, et al. An exemplar imidazoline surfactant for corrosion inhibitor studies: synthesis, characterization, and physicochemical properties [J]. J. Surfactants Deterg., 2020, 23: 225 doi: 10.1002/jsde.12363
30	Umoren S A, Solomon M M, Obot I B, et al. A critical review on the recent studies on plant biomaterials as corrosion inhibitors for industrial metals [J]. J. Ind. Eng. Chem., 2019, 76: 91
31	Dehghani A, Bahlakeh G, Ramezanzadeh B. A detailed electrochemical/theoretical exploration of the aqueous Chinese gooseberry fruit shell extract as a green and cheap corrosion inhibitor for mild steel in acidic solution [J]. J. Mol. Liquids, 2019, 282: 366 doi: 10.1016/j.molliq.2019.03.011
32	Ansari K R, Chauhan D S, Quraishi M A, et al. Bis(2-aminoethyl)amine-modified graphene oxide nanoemulsion for carbon steel protection in 15% HCl: Effect of temperature and synergism with iodide ions [J]. J. Colloid Interface Sci., 2020, 564: 124 doi: 10.1016/j.jcis.2019.12.125
33	Zhang Q, Guo L, Huang Y, et al. Influence of an imidazole-based ionic liquid as electrolyte additive on the performance of alkaline Al-air battery [J]. J. Power Sources, 2023, 564: 232901
34	Zhu M Y, He Z Y, Guo L, et al. Corrosion inhibition of eco-friendly nitrogen-doped carbon dots for carbon steel in acidic media: Performance and mechanism investigation [J]. J. Mol. Liquids, 2021, 342: 117583 doi: 10.1016/j.molliq.2021.117583
35	Zhu M Y, Guo L, He Z Y, et al. Insights into the newly synthesized N-doped carbon dots for Q235 steel corrosion retardation in acidizing media: A detailed multidimensional study [J]. J. Colloid Interface Sci., 2022, 608: 2039 doi: 10.1016/j.jcis.2021.10.160
36	Qiang Y J, Zhang S T, Wang L P. Understanding the adsorption and anticorrosive mechanism of DNA inhibitor for copper in sulfuric acid [J]. Appl. Surf. Sci., 2019, 492: 228
37	Qiang Y J, Guo L, Li H, et al. Fabrication of environmentally friendly Losartan potassium film for corrosion inhibition of mild steel in HCl medium [J]. Chem. Eng. J., 2021, 406: 126863
38	Qiang Y J, Zhang S T, Zhao H C, et al. Enhanced anticorrosion performance of copper by novel N-doped carbon dots [J]. Corros. Sci., 2019, 161: 108193
39	Qiang Y J, Li H, Lan X J. Self-assembling anchored film basing on two tetrazole derivatives for application to protect copper in sulfuric acid environment [J]. J. Mater. Sci. Technol., 2020, 52: 63 doi: 10.1016/j.jmst.2020.04.005
40	Li X H, Xu X, Lei R, et al. Synergistic inhibition effect of walnut green husk extract complex inhibitors on steel in phosphoric acid [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 358
40	李向红, 徐昕, 雷然等. 磷酸中核桃青皮复配缓蚀剂对冷轧钢的缓蚀协同效应 [J]. 中国腐蚀与防护学报, 2022, 42: 358 doi: 10.11902/1005.4537.2021.160
41	Wang F P, Kang W L, Jing H M. Principles, Methods and Applications of Corrosion Electrochemistry [M]. Beijing: Chemical Industry Press, 2008
41	王凤平, 康万利, 敬和民. 腐蚀电化学原理、方法及应用 [M]. 北京: 化学工业出版社, 2008
42	Lei R, Shi C J, Li X H. Corrosion inhibition of aluminum in HCl solution by flos sophorae immaturus extract [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 939
42	雷然, 石成杰, 李向红. 槐米提取物对Al在HCl溶液中的缓蚀作用 [J]. 中国腐蚀与防护学报, 2022, 42: 939
43	Tantawy A H, Soliman K A, Abd El-Lateef H M. Novel synthesized cationic surfactants based on natural piper nigrum as sustainable-green inhibitors for steel pipeline corrosion in CO₂-3.5%NaCl: DFT, Monte Carlo simulations and experimental approaches [J]. J. Cleaner Prod., 2020, 250: 119510 doi: 10.1016/j.jclepro.2019.119510
44	Deng Z H, Lei R, Zhang Z Y, et al. Corrosion inhibition of vetiver extract on steel in hydrochloric acid environment [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 173
44	邓志华, 雷然, 张智勇等. 香根草提取物对冷轧钢在盐酸溶液中的缓蚀作用 [J]. 中国腐蚀与防护学报, 2023, 43: 173 doi: 10.11902/1005.4537.2022.065
45	Douche D, Elmsellem H, Anouar E H, et al. Anti-corrosion performance of 8-hydroxyquinoline derivatives for mild steel in acidic medium: Gravimetric, electrochemical, DFT and molecular dynamics simulation investigations [J]. J. Mol. Liquids, 2020, 308: 113042
46	Hamani H, Daoud D, Benabid S, et al. Electrochemical, density functional theory (DFT) and molecular dynamic (MD) simulations studies of synthesized three news Schiff bases as corrosion inhibitors on mild steel in the acidic environment [J]. J. Indian Chem. Soc., 2022, 99: 100492 doi: 10.1016/j.jics.2022.100492
47	Eze S I, Ibeji C U, Akpan E D, et al. Corrosion performance of Schiff base derived from 2,5-dimethoxybenzyaldehyde: X-ray structure, experimental and DFT studies [J]. Chem. Papers, 2022, 76: 5187 doi: 10.1007/s11696-022-02244-7
48	Shi X, Jiang Y Y, Wang H B, et al. Density functional theory analysis on four pyrazine corrosion inhibitors and their adsorption behavior on Cu(111) surface [J]. CIESC J., 2017, 68: 3211
48	石鑫, 姜云瑛, 王洪博等. 4种吡嗪类缓蚀剂及其在Cu(111)面吸附行为的密度泛函理论研究 [J]. 化工学报, 2017, 68: 3211
49	Chen H B, Li Y C, Zhang X F, et al. Quantum chemistry calculation of corrosion inhibition performance of oleic-acid imidazoline corrosion inhibitors [J]. Corros. Prot., 2014, 35: 1234
49	陈怀兵, 李养池, 张新发等. 油酸基咪唑啉缓蚀剂缓蚀性能和量子化学计算 [J]. 腐蚀与防护, 2014, 35: 1234
50	Zheng T Y, Wang L, Liu J Y, et al. Corrosion inhibition of ionic liquids on the surface of Q235 steel in methanol/sulfuric acid medium [J]. CIESC J., 2020, 71: 2230 doi: 10.11949/0438-1157.20191372
50	郑天宇, 王璐, 刘金彦等. 离子液体在甲醇/硫酸介质中对Q235钢表面的缓蚀性能 [J]. 化工学报, 2020, 71: 2230 doi: 10.11949/0438-1157.20191372
51	Hsissou R, Benhiba F, Abbout S, et al. Trifunctional epoxy polymer as corrosion inhibition material for carbon steel in 1.0 M HCl: MD simulations, DFT and complexation computations [J]. Inorg. Chem. Commun., 2020, 115: 107858
52	Padash R, Sajadi G S, Jafari A H, et al. Corrosion control of aluminum in the solutions of NaCl, HCl and NaOH using 2, 6-dimethylpyridine inhibitor: Experimental and DFT insights [J]. Mater. Chem. Phys., 2020, 244: 122681 doi: 10.1016/j.matchemphys.2020.122681

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